D. Adam & Associates -- Making the difference -- with Steel-Proof corrosion protection.
MATERIAL SAFETY DATA SHEET.- Steel-Proof
SECTION 1: Identification of the substance/mixture and of the company/undertaking.
1.1 Product name :
STEEL PROOF. Semi hard corrosion preventative.
D. Adam & Associates, 1 West End Units, "Charlesfield", St. Boswells, Melrose, TD6 0HH, Scotland, UK.
Tel : +44(0) 1835 268120, Mob : 07880 805478, E-mail: firstname.lastname@example.org
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Product definition :
Mixture (Contains Calcium soap of Oxidised wax, Cas No 68476-81-3)
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3
See Section 11 for more detailed information on health effects and symptoms
2.2 Label elements
Hazard pictograms :
Signal word : Warning H226 -
Hazard statements : Flammable liquid and vapour.
Precautionary statements :
Read label before use. Keep out of reach of children.
If medical advice is needed, have product container or label at hand,
Response : In case of fire: Use alcohol-resistant foam to extinguish
Storage : Keep cool
Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazardous ingredients :
Supplemental label elements :
Special packaging requirements:
SECTION 3: Composition/information on ingredients
Type Product/ingredient name Identifiers % Regulation (EC) No. 1272/2008 [CLP] Type
naphtha (petroleum), EC: 265-150-3 Flam. Liq. 3, H226
hydrotreated heavy CAS: 64742-48-9 10≤25 Asp. Tox. 1, H304 EUH066 
hydrocarbons, C9-C11, CAS: 64742-48-9 5 ≤10 Flam. Liq. 3, H226
n-alkanes, isoalkanes, EC: 265-150-3 Asp. Tox. 1, H304 EUH066 
cyclics, <2% aromatics REACH #: 01-2119463258-33
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
 Substance classified with a health or environmental hazard
SECTION 4: First aid measures
4.1 General :
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. In all cases of doubt, or when symptoms persist, seek medical attention.
Skin contact :
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. In all cases of doubt, or when symptoms persist, seek medical attention. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents or thinners.
If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so that vomit will not re-enter the mouth and throat
Protection of first-aiders :
No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact: No known significant effects or critical hazards.
Irritation: No known significant effects or critical hazards.
Skin contact: Defatting to the skin. May cause skin dryness and irritation.
Ingestion: No known significant effects or critical hazards.
Eye contact: No specific data.
Inhalation: No specific data
Skin contact: Adverse symptoms may include the following: irritation, dryness, cracking.
Ingestion: No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician:
Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments :
No specific data.
SECTION 5: Firefighting measures
Hazardous combustion products :
Hazards from the substance or mixture :
Flammable liquid and vapour. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.
5.1 Extinguishing media Extinguishing media :
alcohol resistant foam, CO2, powders, water spray.
Not to be used : waterjet.
5.2 Special hazards arising from the substance or mixture :
Decomposition products may include the following materials: carbon oxides metal oxide/oxides
5.3 Advice for firefighters:
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.
No action shall be taken involving any personal risk or without suitable training.
Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
Cool closed containers exposed to fire with water.
Do not release runoff from fire to drains or watercourses.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. S
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid breathing vapour or mist. Refer to protective measures listed in sections 7 and 8. No action shall be taken involving any personal risk or without suitable training. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local regulations.
6.2 Environmental precautions:
Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13).
Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same hazard as the spilt product.
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
6.3 Methods and material for containment and cleaning up:
Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Use spark-proof tools and explosion-proof equipment.
Contaminated absorbent material may pose the same hazard as the spilt product.
6.4 Reference to other sections:
See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information. Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid breathing vapour or mist.
Refer to protective measures listed in sections 7 and 8.
No action shall be taken involving any personal risk or without suitable training. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local regulations.
SECTION 7: Handling and storage
7.1 Precautions for safe handling:
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use.
Store and use away from heat, sparks, open flame or any other ignition source.
Empty containers retain product residue and can be hazardous. Do not reuse container.
Never use pressure to empty; the container is not a pressure vessel. Always keep in the same material as the supply container. Good housekeeping standards and regular safe removal of waste materials will minimise risks of spontaneous combustion and other fire hazards.
The Manual Handling Operations Regulations may apply to the handling of containers of this product. Packs with a volume content of 5 litres or more may be marked with a maximum gross weight. To assist employers the following method of calculating the weight for any pack size is given. Take the pack size volume in litres and multiply this figure by the specific gravity (relative density) value given in section 9. This will give the net weight of the coating in kilograms. Allowance will then have to be made for the immediate packaging to give an approximate gross weight.
7.2 Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations. Store in a cool, well-ventilated area away from incompatible materials and ignition sources. Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking. Prevent unauthorized access. Containers that are opened must be carefully resealed and kept upright to prevent leakage.
Do not store below the following temperature: 5 °C
7.3 Specific end use(s)
See separate Product Data Sheet for recommendations or industrial sector specific solutions.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No exposure limit value known.
Recommended monitoring procedures If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required.
Derrived effect levels:
No DELs available
Predicted effect concentrations:
No PECs available.
8.2 Exposure controls
Appropriate engineering controls
All engineering control measures used to control exposure to hazardous substances must be selected, maintained, examined and tested to meet the requirements of the Control Of Substances Hazardous to Health regulations (COSHH). Similarly all personal protective equipment, including respiratory protective equipment, must be selected, issued and maintained to meet the requirements of COSHH. These requirements include the provision of any necessary information, instruction and training with regard to their use. Special precautions should be taken during surface preparation of pre-1960's paint surfaces over wood and metal as they may contain harmful lead. Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of solvent vapour below the relevant workplace exposure limits, suitable respiratory protection should be worn. (See personal protection below). Dry sanding, flame cutting and/ or welding of the dry paint film will give rise to dust and/ or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be worn.
Individual protection measures
Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be worn when soiling is so great that regular work clothes do not adequately protect skin against contact with the product. Safety eyewear should be used when there is a likelihood of exposure.
Hygiene measures :
Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking, using lavatory, and at the end of day.
Eye/face protection :
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts.
If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.
Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The quality of the chemical-resistant protective gloves must be chosen as a function of the specific workplace concentrations and quantity of hazardous substances. Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the appropriate type. Below listed glove(s) should be regarded as generic advice: Recommended: Silver Shield / 4H gloves, nitrile rubber, polyvinyl alcohol (PVA), Viton® Short term exposure: neoprene rubber, butyl rubber, natural rubber (latex), polyvinyl chloride (PVC)
Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved handling this product.
Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If working areas have insufficient ventilation: When the product is applied by means that will not generate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter of type A, when grinding use particle filter of type P. Be sure to use an approved/certified respirator or equivalent.
Environmental exposure controls:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state : Mobile soft gel.
Colour : Brown.
Solubility : Not water miscible
Boiling point :
Odour : Characteristic solvent-like
pH : Testing not relevant or not possible due to nature of the product.
Evaporation rate : Testing not relevant or not possible due to nature of the product.
Meltingpoint/freezing point: Testing not relevant or not possible due to nature of the product
Flash point : Closed cup: 38°C (100.4°F)
Evaporation rate: Testing not relevant or not possible due to nature of the product.
Flammability : Not available.
or explosive limits : 1.4 - 7.6 vol %
Vapour pressure: Testing not relevant or not possible due to nature of the product.
Vapour density : Testing not relevant or not possible due to nature of the product.
Relative density: 0.87 g/cm³
Solubility : Easily soluble in White spirit and hydrocarbon solvents.
Partition coefficient (LogKow) : Testing not relevant or not possible due to nature of the product.
Auto-ignition temperature : Testing not relevant or not possible due to nature of the product.
Decomposition temperature: Testing not relevant or not possible due to nature of the product.
Viscosity: Not applicable
Explosive properties : Testing not relevant or not possible due to nature of the product.
Oxidising properties : Testing not relevant or not possible due to nature of the product.
9.2 Other information
Solvent(s) % by weight : Weighted average: 2 %
Oxidised wax % by weight : Weighted average: 2 %
SECTION 10: Stability and reactivity
10.1 Reactivity :
No specific test data related to reactivity available for this product or its ingredients
10.2 Chemical stability:
This product is stable.
10.3 Possibility of hazardous reactions:
Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid:
Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.
10.5 Incompatible materials:
No specific data.
10.6 Hazardous decomposition products:
When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed: Decomposition products may include the following materials: carbon oxides metal oxide/oxides
SECTION 11: Toxicological information
11.1 Information on toxicological effects
The product has been assessed following the conventional method and is classified for toxicological hazards accordingly. This takes into account, where known, delayed and immediate effects and also chronic effects of components from short term and long term exposure by oral, inhalation and dermal routes of exposure and eye contact.
Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Solvents may cause some of the above effects by absorption through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Product/ingredient name Result Species Dose Exposure
hydrotreated heavy LD50 Oral Rat >2000 mg/kg -
n-alkanes, isoalkanes, cyclics, LD 50 Oral Rat >2000 mg/kg -
Acute toxicity estimates: No known significant effects or critical hazards.
Mutagenic effects: No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Reproductive toxicity : No known significant effects or critical hazards.
Teratogenic : effects; No known significant effects or critical hazards.
Specific target organ toxicity (single exposure)
Product/ingredient name Category hazard Route of exposure Target organs
Hydrocarbons, C9-C11, n-alkanes,
isoalkanes, cyclics, <2% aromatics Category 3 Not applicable. Narcotic effects
Specific target organ toxicity (repeated exposure).
Product/ingredient name Result
Naphtha (petroleum), hydrotreated heavy ASPIRATION HAZARD - Category 1
Hydrocarbons, C9-C11, n-alkanes
isoalkanes, cyclics, <2% aromatics ASPIRATION HAZARD - Category 1
Information on likely routes of exposure:
Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential chronic health effects
SECTION 12: Ecological information
Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
This material should not be allowed into drains, sewers or other water courses.
Product/ingredient name Result Species Exposure
hydrotreated heavy Acute LC50 2200 mg/l Fish 96 hours
12.2 Persistence and degradability
No known data avaliable in our database.
12.3 Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
naphtha (petroleum), hydrotreated heavy - - 10 - 2500 high
high hydrocarbons, C9-C11, n-alkanes,
isoalkanes, cyclics, <2% aromatics - - 10 - 2500 high
12.6. Other adverse effects:
No known significant effects or critical hazards.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
The generation of waste should be avoided or minimised wherever possible. Residues of the product is listed as hazardous waste. Dispose of according to all state and local applicable regulations. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Spillage, remains, discarded clothes and similar should be discarded in a fireproof container. European waste catalogue (EWC) : 08 01 11*.
Used containers, drained and/ or rigorously scraped out and containing dried residues of the supplied coating, are categorised as hazardous waste, with EWC code: 15 01 10*. If mixed with other wastes, the above waste code may not be applicable.
SECTION 14: Transport information
Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by sea, IATA for transport by air.
14.1 14.2 14.3 14.4 14.5
UN no. Proper shipping name Transport hazard class(e) PG Env Additional information
ADR/RID 1268 Petroleum Distillates 3 111 No Special provisions
IMDG 1268 Petroleum Distillates, 3 111 No Tunnel code
IATA 1268 Petroleum Distillates, 3 111 No Emergency schedules
class (EmS) F-E, S-E
14.6 Special precautions for user
Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorisation - Substances of very high concern
None of the components are listed.
Substances of very high concern
None of the components are listed
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles:
Other EU regulations
This product is controlled under the Seveso III Directive
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b C6: Flammable (R10)
15.2 Chemical safety assessment:
This product contains substances for which Chemical Safety Assessments are still required.
SECTION 16: Other information
Abbreviations and acronyms :
ATE = Acute Toxicity Estimate
CLP = Classification,
Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
Other information Full text of abbreviated H statements :
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
Full text of classifications [CLP/GHS] :
Acute Tox. 4, H312 ACUTE TOXICITY (dermal) - category 4
Acute Tox. 1, H304 ASPIRATION HAZARD - category 1
Carc.2, H351 CARCININOGENICITY - Category 2
EUH066 Repeated exposure may cause skin dryness or cracking.
Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3
Skin Sens. 1, H317 SKIN SENSITIZATION - Category 1
STOT SE 3, H336 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification: FLAMMABLE LIQUIDS - Category 3 Justification : On basis of test data
UK REGULATORY REFERENCES:
The products are classified and supplied in accordance with the Chemicals (Hazard Information Packaging for supply) regulations (CHIP). The information contained in this safety data sheet does not constitute the user's own assessment of workplace risks as required by other health and safety legislation. The provision of the Health and Safety at Work Act and the Control of Substances Hazardous to Health regulations apply to the use of this product at work.
Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Classification, labelling and packaging of substances and mixtures 1272/2008EC.
APPROVED CODE OF PRACTICE:
Approved classification and labelling guide (Sixth edition) The compilation of safety data sheets (Third edition). GUIDANCE NOTES:
Workplace Exposure Limits EH40. Storage of Flammable Liquids in Containers, HS(G)51 Storage of Packaged Dangerous Substances, HS(G)71.
The Control Of Substances Hazardous to Health regulations (as amended) The Manual Handling Operations regulations (as amended) The Environmental Protection (Duty of Care) regulations (as amended) The Chemicals (Hazard Information and Packaging) for supply regulations (as amended) The Health and Safety at Work act 1974 (as amended).
Notice to reader:
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee of the technical preformance or suitability for particular applications. It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.